Ok - you asked for it alphasierra. It's a bit difficult to really explain without being able to show spectral curves, etc., but here goes........
I'll rely on 30+ years of managing a chemical technical service lab that was involved to the greatest extent with color matching - coming up with a dye/pigment formula that would match a colored sample sent in by a customer that they wanted to duplicate. I'll try to be as non-technical as possible.
The reason that it can be difficult to get an accurate test result is due to a term in the color industry called metamerism. Metamerism is when you get two colors that match under one light source, but do not match under a different light source. Common light souces for us are Daylight, Incandescent (typical light bulb), and Fluorescent. Each of these light sources has a different energy spectrum. For instance, a common incandescent light bulb actually has most of the energy it emits in the red region of the visible light spectrum. Hard to beieve but true - it also emits no UV (blacklight) energy. Daylight is very high in UV energy, and fluorescent lights have varying amounts of UV energy, depending on the type of fluorescent bulb.
When matching a color, and wanting to get a non-metameric match (a match under all light sources) it is almost necessary to be able to use the same dyes or pigments that were used in the standard color that is being matched. Often this isn't possible and we end up with a non-metameric match - one that looks good in daylight perhaps, but doesn't even look close to the standard color under incandescent lighting or under fluorescent lighting.
An example would be shopping for clothes - you pick out two things that look like the colors match in the store, but later find that the colors don't go together very well when you wear the clothes outside under daylight. This is due to the different pieces of those clothes being dyed with different dyes, and each dye has it's own specific spectrum of what colors it will absorb from the light source, and which colors it reflects back to your eyes. Add in the differences of light energies emitted by various light sources, and it complicates the matter further.
On to the color matching type tests used for our water parameters........
For those tests that rely on using a supplied printed color card to compare your colored test solution against, you'll find that your test result can vary if you look at the colors under an incandescent light, then walk over next to a window with daylight.
As an example, I've seen quite a difference in pH test results when comparing the color of my test result solution versus the colors on the printed card, just by taking my card and test result from under my kitchen incandescent lights over to the patio door and viewing under daylight. This is due to the colors on the little card being printed with insoluble colored pigments, and the color in your test solution being a color more closely related to that of a water soluble dye.
In the industry that I work in it is just about impossible to get a non-metameric color match if your color standard was made with colored pigments, and the only choice you have to match that color is water soluble dyes. We'd end up with a color match that might look good under daylight, but not match at all under incandescent or fluorescent lighting. Same problem when using the tests that come with the printed color cards.
I don't know the answer. I guess it depends on the lighting conditions under which the test manufacturer developed his test. Most, if not all, don't tell you under what type of lighting the card and your sample should be viewed. It's the reason I went with a pH meter and got rid of the color card/solution type of test.
Tests using a titration and a color change of the solution aren't affected by this problem (such as most Ca and Alk tests). It's the tests that rely on you to compare a colored solution against a printed card that are affected by this problem.
Should I add in the problem that as we age most of us get what's commonly called "red eye" and we don't see colors the same as a younger person does?