All great points sirrealism.
If this ceramic doesn't have aluminum in it, then it probably isn't the culprit. That is, if the manufacturer is telling the truth, which at this point I have no evidence to the contrary. But, I do wonder as the blocks get older, if it starts to degrade? And while degrading it releases stuff into the tanks water. If so, then buying a new block after a years time should counter act this issue.
I am more inclined to bet that these friends of yours may have used other products that are known to have aluminum in them. Aluminum is used to absorb phosphate, as such it is in many products available to absorb phosphate from our tanks. And those who have sps tanks usually try to keep phosphate levels really low and one way to do that is to use phosphate removing products. And one of the best products out there to remove phosphate are the ones w/aluminum in them b/c it is so effective: it produces results.
I just dug up two articles that I had read a while ago, thought you'd find them interesting:
Chemistry And The Aquarium: Aluminum In The Reef Aquarium
Product Review: Ferrous Oxide Phosphate Removers
From the articles, items to note include:
- Most often, aluminum comes up during discussions of aluminum-based phosphate binding agents.
- These aluminum oxide materials have been reported to cause negative reactions in certain corals, and one hypothesis that has been suggested is that aluminum is released that irritates the corals.
- Aluminum is indeed released from one of these types of materials (Phosguard, sold by Seachem)
- Inputs of Aluminum in Reef Aquaria can come from: Salt Mixes, Food, Ca and Alk supplements, and other items like phosguard
- It appears that the release of aluminum could be the cause of the effects that some folks have seen in aquaria when using aluminum-based phosphate and silicate absorbing materials. However, only a larger study could definitively demonstrate that to be the case.
"For many years reef hobbyists have had success lowering excessively high phosphate levels with products such as SeaChem's PhosGuard. Some hobbyists, however, have avoided using this type of phosphate remover because they use aluminum oxides to bind the phosphate. Aluminum oxide does remove phosphate, but isn't an ideal product for a reef tank. First, while aluminum oxide can reduce seriously high phosphate levels, it often leaves enough phosphate in the water for nuisance algae to remain a problem. A second issue is the presence of aluminum in the filter material. The material has to be washed thoroughly to remove fine aluminum particles, but even if washed the material can increase aluminum levels in a tank."
Here is SeaChem's PhosGuard website listing aluminum in their product:
http://www.seachem.com/Products/product_pages/PhosGuard.html