I am not talking about adsorption at all. Well, briefly , when I stated I use GAC for removal of color from my water. I merely am speaking about the studies that show the alledged effectiveness of these different medias as substates for denitrification.
Let me be clear on this one last time. In this hobby and 95 % of the time in the waste water industry, it is used for chemical adsorption and mechanical filtration. ANY porous media can be used for biological filtration. And no one in this hobby, I'm aware of, uses GAC for biological filtration, as it is counter productive and is a poor media for facultative subanerobic denitrification. It is just to porous and usually just allows the NO3 to increase due to massive bio-mineralization and nitrification.
I am quite aware that natural zeolite do not adsorb in fresh water, and did not say or imply that they did.
How can you claim to be a civil engineer and water filtration expert, so to speak and make that statement, which is shear nonsense. Natural Zeolites an artificial Zeolites are mined or manufactured but the '10's - thousands of tons /year to filter FRESH WATER for the adsorption of unwanted ions. What do you think water softeners use ? Even large water treatment plants sues them to remove toxic ions and heavy metals. Zeolites are on of the most if not the most heavily mined *mineral in the world. It is usual the mineral Clinoptilolite. Zeolites are ion exchange minerals, which are at their height in freshwater.
If you insist that I am talking out my heiny I can probably find the article about testing of these medias as substrates for biological filtration.
I have such articles that is not the issue it is how GAC or zeolites are used in THIS hobby.
I only use GAC and zeolites as adsorber but they study/tests I m referring to still exists.
Again how did you miss this ? Zeolites, in short, will be dead as ion exchangers in seawater due to the massive amount of ions in seawater. They will be about dead the first minute in seawater in most cases. Even a simple glucose molecule is hard to fit into a pore. There is no known bacteria that can fit into a zeolite pore. It is like trying to stick a watermelon up ones butt. However, some Zeolites do have what we call "Void Fraction" which is the amount of void spaces or channels, which are not part of the pore structure, where some bacteria can fit it and the can be some mechanical filtration. This is what the ZeoVit System is all about for SPS tanks. However, the Zeolites have to be cleaned every day of the mulm/ bio-films which are "washed off and fed to the corals an the rest is exported via skimming.
I am quite aware of what GAC is typically used for, I am a civil engineerr with an emphasis in environmental engineering, which means I work in the design and running of water and waste treatment plants.
Sorry but I'm beginning to have extreme doubts base on your answers to this post and others.
It is not a far stretch to look at these media as substrates for biological filtration. Seems like a logical thing to test or study consideringthe porousity and therefore surface areas of thes medias.
It is not a stretch at all and can be used for bio, will go bio and is even used in the waste water industry for that very purpose at times but not in this hobby. It is self-defeating and just raises NO3-.
The fact is we are not even discussing the same things (tests/studies)before you are out of line trying to imply what iI might or might not know. Period.
The only one here out of line is yourself an all your errors and not understanding the subject matter at hand, which is quite evident.
I do not post all reference studies nor do you so obviously if my opinions are not based on scietifi methods then your surely are not either.
I have posted lots of studies on this forum to include, RF, RC and others on Zeolites and GAC, just do a search on them. You have not posted a single one at all. Feldman's studies will be based on the adsorption of organics in seawater and the those we have to deal with. Here is two of his first ones on GAC.
Advanced Aquarist's Online Magazine - Feature Article: Granular Activated Carbon, Part 1: Modeling of Operational Parameters for Dissolved Organic Carbon Removal from Marine Aquaria
Advanced Aquarist's Online Magazine - Feature Article: Granular Activated Carbon, Part 2: Modeling of Operational Parameters for Dissolved Organic Carbon Removal from Marine Aquaria