The pH of the water is a measure of the balance between the Hydrogen (H+) and Hydroxide (OH) ions in the water...The alkalinity is a measurement of the waters buffering ability, or its ability to absorb and neutralize acid...The normal trend for pH in a saltwater system is downward, or more acidic, which stems from the addition of acids into the aquarium. These acids come from several sources, the primary ones being: (1) excess carbon dioxide (CO2) from respiration caused by lack of sufficient gas exchange, (2) nitric acid from biological filtration (nitrification), and (3) organic acids from metabolic wastes.