Sas said it best...what else is new? lol
If you are using an rodi unit it will be removing 99% of all of what is going through it. Your calcium and mg will be coming from the salt that you use and replaced with water changes. By trying to rely on the city or well water to keep up either is just asking for one more variable that you will never have any control over whatsoever.
As you may already be aware, their are a ton of variables out of our control in this thing we call reefing. Why add anything within your control?
Hope this helps and have fun!