JNicho with all due respect I find your "blog/article just a bit to ... opinionated and lacking in tests & proof one way or the other.
You stated
Well, guess what, there is no invisible barrier between substances in the sand and the rest of the system.
Well then how do you explain the differentiation between the aerobic zone and anaerobic zone
(which you did indeed mention) in the sand bed? It's not a distinct LINE but a gradual differentiation as you get deeper into the sand. What happens is that these "locked in" substances are either processed or slowly released into the system over long periods of time and not all at once during a deep cleaning session.
In a stable and mature tank if you do go about digging and cleaning into the DEEPER regions of a DSB you will release the "Pockets" of built up gases . I don't have scientific proof but I can tell you from experience those gases are present and some-what locked in. I've removed/replaced sandbeds and when you dig into the deeper layers there is no way of denying what's being released into the tank (smells like rotten eggs).
If someone wants to "clean/siphon" their sandbed then it should be done from the beginning and maintained that way. I believe that even remotely hinting that someone should dig in and start cleaning an established DSP into the deeper regions of their DSB is asking for serious problems.
Now I'm not saying DSB's are perfect or am I saying they are terrible. There is no IDEAL substrate yet but I'm afraid that telling someone
(paraphrasing here) "It's a good idea to start digging into your DSB today with a Gravel-Vac" could lead to some serious tank problems and even crashes.