I've been puzzled by the calcium/alkalinity relationship for over two years now.
Take a look at this article -
Chemistry and The Aquarium -Calcium and Alkalinity
You seem to be in zone 4.
When I was in zone 4 I just let it ride...and did a few extra water changes. After a few months the extra high calcium reduced to normal.
Since then....Both of my tanks have fallen into zones 2 and 3....with low Alk and low calcium..... I've never had a problem with PH though, that has always been 8.2.
I can't seem to get my calcium to stay above 300ppm....and cant get Alk to stay above 2.0! I've been using Kent calcium and baking soda. Anyone have any product reccomendations?