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New Frontiers This is the forum to discuss new ideas and advanced topics in reefkeeping.

View Poll Results: which is of the most concern in keeping a reef
Controling elements of the nitrogen is my foremost concern 13 34.21%
elements of phosphates are my foremost concern 15 39.47%
nitrogen is the limiting factor in life 3 7.89%
phosphate is the limiting factor in life 7 18.42%
Voters: 38. You may not vote on this poll

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Old 12-20-2003, 01:45 PM   #16 (permalink)
ScottT1980
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Just to keep you honest Alberto

Quote:
amino acids that compose DNA and RNA.
Did you mean nucleic acids? Interestingly, phosphate esters are also in the structure of DNA, but that is getting a bit too intensive for the sake of this discussion. No trying to be a smart a**, just wanted to clarify (honestly, I don't remember if there are any amino acids in the structure of RNA or DNA).

Am I missing something else here... Are high levels of phosphates toxic to our fish or inverts? If the primary concern is their ability to promote massive amounts of algae growth, then I am not "in the dark" and I would say that nitrogen is still my primary concern but if in fact I have missed something, then I might change my mind.

Also, I know Nikki mentioned it in another thread but does anyone know anything about xenia's absorption of PO4 and perhaps the use of xenia vs. macro?

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Old 12-20-2003, 03:00 PM   #17 (permalink)
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Quote:
Am I missing something else here... Are high levels of phosphates toxic to our fish or inverts? If the primary concern is their ability to promote massive amounts of algae growth, then I am not "in the dark" and I would say that nitrogen is still my primary concern but if in fact I have missed something, then I might change my mind.
Based on this comment, you are overlooking the fact that high levels of PO4 will inhibit calcification in corals and other Ca-consuming organisms (Coralline for example).
So indirectly, yes, PO4 can be detrimental to corals, but not necessarily fish or many inverts.

-HTH-
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Old 12-20-2003, 03:41 PM   #18 (permalink)
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Nice piece Alberto

As one can see they are both limiting factors. Advanced seaweed biology books usually have a whole chapter on each. As far as concentration Carbon by far out weighs Phosphorus. The ratio of C in seaweeds, to that in water is 1.0 x 10-4 and P is 2.4 x 10-5. They are both part of Liebig's Law of Minimum, as are other nutrients. That avg ratio of C:P in seaweeds is almost 100 : 1 (97.86 : 1)or 274, 000 ug / g-l C and 2,800 ug /g-l P
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Old 12-20-2003, 03:51 PM   #19 (permalink)
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Wow this has turned into a neat conversation, which is really neat concidering I completely blew the question I was try to ask, lol

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Old 12-20-2003, 04:47 PM   #20 (permalink)
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Quote:
Based on this comment, you are overlooking the fact that high levels of PO4 will inhibit calcification in corals and other Ca-consuming organisms (Coralline for example).
Yes, we also have to consider (thanks Cosmic for reminding me)that but I guess my ultimate concern regards toxicity and nitrogenous wastes are toxic and can immediatly impact our system's inhabitants whereas PO4 can only hinder their growth.

Quote:
Advanced seaweed biology books usually have a whole chapter on each. As far as concentration Carbon by far out weighs Phosphorus. The ratio of C in seaweeds, to that in water is 1.0 x 10-4 and P is 2.4 x 10-5. They are both part of Liebig's Law of Minimum, as are other nutrients. That avg ratio of C:P in seaweeds is almost 100 : 1 (97.86 : 1)or 274, 000 ug / g-l C and 2,800 ug /g-l P
I could be wrong but I think this ratio holds for most terrestrial plants as well. What is amazing is how very little phosphate can greatly increase growth rates (or at least from what I have read). And then there was the whole fiasco with phosphates and the Great Lakes...

Take er easy
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Old 12-20-2003, 07:16 PM   #21 (permalink)
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I gues it would have to do with which form of phosphorus we are talking about, DPI,PPI,DPO,DPO. Another thing to look at when it come to phosphates is the fact bacteria actually produce it
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Old 12-20-2003, 08:47 PM   #22 (permalink)
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Mojo

You have those letters out of order Must be your time for a bad day, mine has been all week, so you have allot of catching up to due



DPI,PPI,DPO,DPO

DIP, PIP, DOP, POP.

DOP is the worst and casues most of the problems in the end and you can't measure it, unless you have the test kit I have Most kits measure DIP = PO4 only. All that stuff above is called Total P.
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Old 12-20-2003, 09:22 PM   #23 (permalink)
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You know that is the way we always used to say them, but I know from the chemical terminaolgy you are correct, thanks, lol.
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Old 12-21-2003, 03:46 AM   #24 (permalink)
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My ReefSpace
Add yours!
Great stuff everyone! Thanks!

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Old 12-21-2003, 08:04 AM   #25 (permalink)
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Yes, you were right. It is nucleic acids. Forgive my dislexia. I guess the small strokes I get daily must have been kicking in.
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Old 01-18-2004, 05:01 AM   #26 (permalink)
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Heh, as far as I'm concerned, phosphates and nitrogen aren't a problem... They're an adventure.
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Old 07-12-2004, 11:58 PM   #27 (permalink)
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Wow, cant believe I've just found this thread....
Thanks David for resurrecting it and bringing it (inadvertantly) to my attention!
Mike, Boomer, Dgasmd, Scott1980, Cosmic et al...
So I know that I need to whatch out for both phosphates and nitrogen compounds, but is one really more dangerous than another? I know based on alot of reading about phosphates lately that its probably the toughest to control, but it can be managed.
I know Mike has a Deltec reactor for Rowa media, but do you feel the smaller phosban reactor is worth using on smaller systems? How would you employ PO4 removing media in a smaller BB set up for SPS? Would the PO4 reactor be all that was used or what?
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Old 07-13-2004, 06:17 AM   #28 (permalink)
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Controlling Phosphates to stop algae growth. I have it on my plate coral at the moment. My fault. Let a water change slip 2 months and that's the result. Doh
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Old 07-13-2004, 10:56 AM   #29 (permalink)
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Nitrogen is limiting in freshwater IMO.

Phosphates are limiting in saltwater IMO.
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Old 07-13-2004, 10:58 AM   #30 (permalink)
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Yea this is an old thread I started way back when we were going over various filtration systems. I did it to get a feel for how folks percieved various problems with in thier tanks and to see where thier priorities were.
In the wild nitrogen is everywhere and is quite common, plus thier is a ton of things that can deal with it and eliminate it. Also nitrates can be made from scratch in our tanks so its not truely limiting. WIth the ammount of cyanos we have in oour tanks its be manufactured all the time.
In regards to Phosphates they are limited by how much we truely put into our tanks. So when you compare the two in our reef tanks P is truely limiting.

Nick using a PO4 reactor with phosban or rowa is just one part of the overall battle against total P. It will suck up any available PO4 that passes through it, so yes it could play a part in the over all game.


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